211216 Organometallchemie: Grundlage und Katalyse (V) (WiSe 2022/2023)
Contents, comment
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Diese Veranstaltung bietet grundlegende Kenntnisse über Struktur, Stabilität und Reaktivität der Übergangsmetallkomplexen mit besonderem Schwerpunkt auf deren Anwendungen in der Katalyse an.
Struktur und Bindung katalytisch relevanter Metalkomplexe
Liganden: Ligandentypen, σ/ π-Hinbindung, ηx-Haptiziät etc.
M–M Bindung (M = Metall)
M–L Mehrfach Bindung (L = Ligand)
M–C Bindung: Type und Eigenschaften
Stabilität und Reaktivität: 18-Elektronenregel, Isolobale Beziehungen
Katalyse mit Übergangsmetall-Komplexen
Katalysatortypen, Grundbegriffe (STY, TON, TOF etc.)
Reaktionen-Mechanismen
Katalytische Zyklen
Aktivität und Selektivität (Chemo-, Regio-, Diastereo- und Enantio-Selektivität) und Steuerung
Anwendung von Katalysatoren in der Industrie: Fischer-Tropsch-Synthese, Olefin-Metathese, Shell Higher
Olefin Process (SHOP), Olefin-Oxidation (Wacker-Verfahren)
Aktuelle Forschungstrends (Kohlenstoff-basierte Liganden, Nachhaltige Katalyse)
Teaching staff
Dates ( Calendar view )
| Frequency | Weekday | Time | Format / Place | Period |
|---|
Subject assignments
| Module | Course | Requirements | |
|---|---|---|---|
| 21-M-C1.1 Synthese - Theorie - Basis | Veranstaltungen Synthese - Theorie - Basis 4 LP | - | Student information |
| 21-M-C1.2 Synthese - Theorie - Erweiterung | Veranstaltungen Synthese - Theorie - Erweiterung 4 LP | - | Student information |
| 21-M-C1.3 Synthese - Theorie - Spezialisierung | Veranstaltungen Synthese - Theorie - Spezialisierung 4 LP | - | Student information |
| 21-M-C1.4 Synthese - Theorie - Erweiterung - 5 LP | Veranstaltungen Synthese - Theorie - Erweiterung 4 LP | - | Student information |
| 21-M-C1.5 Synthese - Theorie - Spezialisierung - 5 LP | Veranstaltungen Synthese - Theorie - Spezialisierung 4 LP | - | Student information |
The binding module descriptions contain further information, including specifications on the "types of assignments" students need to complete. In cases where a module description mentions more than one kind of assignment, the respective member of the teaching staff will decide which task(s) they assign the students.
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