Cooling with molecules
Researchers at the universities in Bielefeld, Manchester, and Zaragoza present low-temperature experiment in Nature Communications
An international team of scientists have become the first ever researchers to successfully reach temperatures below minus 272.15 degrees Celsius – only just above absolute zero – using magnetic molecules. The physicists and chemists are presenting their new investigation today (22 October 2014) in the scientific journal Nature Communications. It was developed by six scientists from Bielefeld University, the University of Manchester (Great Britain), and the Universidad de Zaragoza (Spain).
Scientists usually express temperatures on the Kelvin scale. Minus 272.15 degrees Celsius is precisely one Kelvin. This is why the researchers call their development ‘sub-Kelvin cooling’. Cold temperatures are generally obtained by using an effect that anyone can observe with an aerosol can. If you press the button on the can for long enough, you will notice that whatever is being sprayed out gets colder. A normal refrigerator also uses this effect. In both cases, a gaseous refrigerant cools down as it expands due to the drop from high to low pressure.
But how can we reach really low temperatures in the low Kelvin range? Nowadays, this is done by using helium as the refrigerant. However, helium is becoming increasingly scarce. ‘The very rare helium-3 isotope with which one can also get down to a few tenths of a Kelvin is now practically unaffordable,’ says Professor Dr. Jürgen Schnack, co-author of the study and physicist at Bielefeld University. Magnetic substances can also be used as refrigerants. These particularly include paramagnetic salts. Their cooling has nothing to do with pressure. They cool down when the external magnetic field generated by, for example, an electromagnet decreases. When the electric current is reduced in the coil, the magnetic field also decreases and the paramagnetic salts cool down.
The magnetic molecule with which he and his colleagues have been experimenting is called ‘Gd7’ in short. Very appropriately, it has the geometric structure of a snowflake. As the computer simulations by Professor Schnack‘s research team show, it starts of by cooling down in a decreasing magnetic field; then it warms up again before finally cooling down once more as the magnetic field disappears. ‘We were really excited when the theoretical computations were able to explain this complex behaviour in detail,’ says the Professor of Theoretical Physics. ‘Compared to paramagnetic salts in which the temperature drops continuously as the magnetic field declines, molecules such as Gd7 behave in more complex ways. They can be used to get down to really low temperatures without switching off the magnetic field completely,’ reports Dr. Marco Evangelisti whose team at the Universidad de Zaragoza carried out the low-temperature experiments.
Jürgen Schnack has been studying magnetic molecules for 15 years. These often, but not always, have an organic backbone composed of carbon, hydrogen, and oxygen in which special metal ions such as iron ions are bound together. Each of these iron particles functions as a tiny magnetic needle with neighbouring particles working together like a larger magnet. The goal of research on magnetic molecules is to design them so that they exactly fit various applications: as transparent magnets, as nano data memoires, or even as cooling molecules.
Joseph W. Sharples, David Collison, Eric J. L. McInnes, Jürgen Schnack, Elias Palacios, Marco Evangelisti: Quantum signatures of a molecular nanomagnet in direct magnetocaloric measurements. Nature Communications, www.nature.com/ncomms/2014/141022/ncomms6321/full/ncomms6321.html, http://dx.doi.org/10.1038/ncomm6321, published on 22 October 2014.
Further information is available online at:
Prof. Dr. Jürgen Schnack, Bielefeld University
Faculty of Physics
Telephone 0521 106-6193, -6901 (secretary's office)